谢明惠
姓名 谢明惠
电子邮件 mshieh@ntnu.edu.tw
联络电话 (02)77496118
个人网址 https://ntnud405b.wixsite.com/mshieh
实验室电话 (02)77496187; (02)77496188
职称 特聘教授
研究领域 金属簇化学、有机金属、催化反应、计算化学
学术专长
  • 奈米级金属簇半导体之制成与光电特性研究。
  • 金属簇化合物活化小分子(例如：CO2、CO、O2、H2、MeOH)之反应探讨。
  • 新型金属簇化合物的合成开发与其电化学及磁性的探讨。
  • 金属簇化合物之有机催化反应。 DFT理论计算。
实验室 奈米金属簇研究室

学术着作

    1. M. Shieh,* Y.-H. Li, C.-H. Lin and T.-Y. Sun, “Low-Valent, Multiply Bonded, Trigonal-Planar Sb Complex: Rational Syntheses, Dual Acidic/Basic Properties, and Unexpected Semiconducting Characteristics,” Inorg. Chem. 2020, 59, 16073. [10.1021/acs.inorgchem.0c02820]
    2. M. Shieh,* Y.-H. Liu, T.-S. Lin, Y.-C. Lin, W.-K. Cheng and R. Y. Lin, “Manganese Telluride Carbonyl Complexes: Facile Syntheses and Exotic Properties—Reversible Transformations, Hydrogen Generation, Paramagnetic, and Semiconducting Properties,” Inorg. Chem. 2020, 59, 6923. [10.1021/acs.inorgchem.0c00412]
    3. M. Shieh,* Y.-H. Liu, Y.-H. Li and R. Y. Lin, “Metal Carbonyl Cluster-Based Coordination Polymers: Diverse Syntheses, Versatile Network Structures, and Special Properties,” CrystEngComm 2019, 21, 7341. [10.1039/C9CE01539F] Back Cover 
    4. M. Shieh,* Y.-H. Liu, C.-C. Wang, S.-H. Jian, C.-N. Lin, Y.-M. Chen and C.-Y. Huang, “A Comparative Study on NHC-Functionalized Ternary Se/Te–Fe–Cu Compounds: Synthesis, Catalysis, and the Effect of Chalcogens,” New J. Chem. 2019, 43, 11832. [10.1039/c9nj02051a] 
    5. M. Shieh,* Y.-H. Liu, C.-C. Wang, S.-H. Jian, C.-N. Lin, Y.-M. Chen and C.-Y. Huang, “A Comparative Study on NHC-Functionalized Ternary Se/Te–Fe–Cu Compounds: Synthesis, Catalysis, and the Effect of Chalcogens,” New J. Chem. 2019, 43, 12191. [10.1039/C9NJ90106J] Back Cover
    6. M. Shieh,* Y.-H. Liu, C.-Y. Huang, S.-W. Chen, W.-K. Cheng and L.-T. Chien, “The First Naked Bismuth–Chalcogen Metal Carbonyl Clusters: Extraordinary Nucleophilicity of the Bi Atom and Semiconducting Characteristics,” Inorg. Chem. 2019, 58, 6706. [10.1021/acs.inorgchem.9b00080] Supplementary Cover
    7. M. Shieh,* Y.-H. Liu, Y.-H. Li, C.-N. Lin and C.-C. Wang, “Functionalized NHC-incorporated Te─Fe─Cu clusters: Facile synthesis, electrochemistry, and catalytic reaction,” J. Organomet. Chem. 2018, 867, 161. [10.1016/j.jorganchem.2017.10.039]
    8. M. Shieh,* C.-C. Yu, K.-J. Hsing and W.-J. Chang, “A Multiply Bonded Trigonal-Planar Bismuth(III) Complex: Prodigious Lewis Acidity, Solvatochromism, Etherification, and Semiconducting Characteristics,” Chem. Eur. J. 2017, 23, 11677. [10.1002/chem.201702396]
    9. M. Shieh,* C.-C. Yu, C.-Y. Miu, C.-H. Kung, C.-Y. Huang, Y.-H. Liu, H.-L. Liu* and C.-C. Shen, “Semiconducting Coordination Polymers Based on the Predesigned Ternary Te─Fe─Cu Carbonyl Cluster and Conjugation-Interrupted Dipyridyl Linkers,” Chem. Eur. J. 2017, 23, 11261.[10.1002/chem.201701257] Selected as a Hot Paper; [10.1002/chem.201702641] Front Cover
    10. C.-N. Lin, C.-Y. Huang, C.-C. Yu, Y.-M. Chen, W.-M. Ke, G.-J. Wang, G.-A. Lee* and M. Shieh,* “Iron Carbonyl Cluster-Incorporated Cu(I) NHC Complexes in Homocoupling of Arylboronic Acids: An Effective [TeFe3(CO)9]2- Ligand,” Dalton Trans. 2015, 44, 16675. [10.1039/c5dt03242c]
    11. M. Shieh,* C.-Y. Miu, K.-J. Hsing, L.-F. Jang and C.-N. Lin, “Copper-incorporated mono- and di-TeRu5 Metal Carbonyl Complexes: Syntheses, Structures, and An Unusual Skeletal Arrangement,” Dalton Trans. 2015, 44, 6526. [10.1039/C5DT00546A]
    12. M. Shieh,* Y.-Y. Chu, L.-F. Jang and C.-H. Ho, “CO and CO2 Fixation by Se─Ru─CO Hydride Clusters,” Inorg. Chem. 2014, 53, 4284. [10.1021/ic500821z]
    13. C.-N. Lin, W.-T. Jhu and M. Shieh,* “Vapochemically and Mechanochemically Reversible Polymerization/Depolymerization of S─Fe─Cu Carbonyl Clusters,“ Chem. Commun. 2014, 50, 1134. [10.1039/c3cc48303g]
    14. M. Shieh,* C.-H. Yu, Y.-Y. Chu, Y.-W. Guo, C.-Y. Huang, K.-J. Hsing, P.-C. Chen and C.-F. Lee, “Trigonal Bipyramidal and Square Pyramidal Chromium─Manganese Chalcogenide Clusters [E2CrMn2(CO)n]2─ (E = S, Se, Te; n = 9, 10): Synthesis, Electrochemistry, UV/Vis Absorption, and Computational Studies,” Chem. Asian J. 2013, 8, 963. [10.1002/asia.201201163]
    15. M. Shieh,* C.-Y. Miu, Y.-Y. Chu and C.-N. Lin, “Recent Progress in the Chemistry of Anionic Groups 6─8 Carbonyl Chalcogenide Clusters,” Coord. Chem. Rev. 2012, 256, 637. [10.1016/j.ccr.2011.11.010]
    16. M. Shieh,* C.-Y. Miu, K.-C. Huang, C.-F. Lee and B.-G. Chen, “Stepwise Construction of Manganese-Chromium Carbonyl Chalcogenide Complexes: Synthesis, Electrochemical Properties, and Computational Studies,” Inorg. Chem. 2011, 50, 7735. [10.1021/ic200885h]
    17. M. Shieh,* Y.-Y. Chu, M.-H. Hsu, W.-M. Ke and C.-N. Lin, “Lead-Chromium Carbonyl Complexes Incorporated with Group 8 Metals: Synthesis, Reactivity, and Theoretical Calculations,” Inorg. Chem. 2011, 50, 565. [10.1021/ic101560u]
    18. C.-H. Ho, Y.-Y. Chu, C.-N. Lin, H.-W. Chen, C.-Y. Huang and M. Shieh,* “Selenium─Manganese Carbonyl Clusters: Synthesis, Reversible Transformation, Electrochemical Properties, and Theoretical Calculations,” Organometallics 2010, 29, 4396. [10.1021/om1006819]
    19. M.Shieh,* C.-N. Lin, C.-Y. Miu, M.-H. Hsu, Y.-W. Pan and L.-F. Ho, “Chromium-Manganese Selenide Carbonyl Complexes: Paramagnetic Clusters and Relevance to C=O Activation of Acetone,” Inorg. Chem. 2010, 49, 8056. [10.1021/ic101118y]
    20. M. Shieh,* C.-H. Ho,W.-S. Sheu* and H.-W. Chen, “Selective Insertion of Oxygen and Selenium into an Electron-Precise Paramagnetic Selenium─Manganese Carbonyl Cluster [Se6Mn6(CO)18]4−,” J. Am. Chem. Soc. 2010, 132, 4032. [10.1021/ja9091566]
    21. M. Shieh,* Y.-Y. Chu, C.-Y. Miu, P.-F. Wu and T.-M. Zeng, “Bimetallic Ru-Cu Tellurido Complexes: Controlled Synthesis and Electrochemical Studies of Copper Halide-TeRu5 and Te2Ru4 Clusters,”Dalton Trans. 2010, 39, 1492. (Selected as a Hot Article) [10.1039/b919176c]
    22. B.-G. Chen, C.-H. Ho, C.-J. Lee and M. Shieh,* “Copper Halide-Incorporated Tellurium─Iron Carbonyl Complexes: Transformation, Electrochemical Properties, and Theoretical Calculations,” Inorg. Chem. 2009, 48, 10757. [10.1021/ic901647n]
    23. M. Shieh,* C.-H. Ho, W.-S. Sheu*, B.-G. Chen, Y.-Y. Chu, C.-Y. Miu, H.-L. Liu and C.-C. Shen, “Semiconducting Tellurium–Iron–Copper Carbonyl Polymers,” J. Am. Chem. Soc. 2008, 130, 14114. [10.1021/ja8065623]
    24. M. Shieh,* C.-Y. Miu, C.-J. Lee, W.-C. Chen, Y.-Y. Chu and H.-L. Chen, “Construction of Copper Halide-Triiron Selenide Carbonyl Complexes: Synthetic, Electrochemical, and Theoretical Studies,” Inorg. Chem. 2008, 47, 11018. [10.1021/ic8012552]
    25. M. Shieh,* M.-H. Hsu, W.-S. Sheu, L.-F. Jang, S.-F. Lin, Y.-Y. Chu, C.-Y. Miu, Y.-W. Lai, H.-L. Liu and J.-L. Her, “A New Series of Copper Halide-Bridged Ruthenium Telluride Carbonyl Complexes: Discovery of a Unique Semiconducting Cluster Chain Polymer [{PPh4}2{Te2Ru4(CO)10Cu4Br2Cl2}·THF]¥,” Chem. Eur. J. 2007, 13, 6605. [10.1002/chem.200700135]
    26. M. Shieh,* L.-F. Ho, P.-C. Chen, M.-H. Hsu, H.-L. Chen, Y.-W. Guo, Y.-W. Pan and Y.-C. Lin, “Reaction of [Et4N]2[Te{Cr(CO)5}n] (n = 2, 3) toward Electrophiles: Reactivity Comparison and Theoretical Calculations,” Organometallics 2007, 26, 6184. [10.1021/om700789a]
    27. M.-H. Hsu, R.-T. Chen, W.-S. Sheu and M. Shieh,* “Carbon Dioxide Fixation by an Unprecedented Hydroxo Lead-Chromium Carbonyl Complex: Synthesis, Reactivity, and Theoretical Calculations,” Inorg. Chem. 2006, 45, 6740. [10.1021/ic060554o]
    28. Y.-W. Lai, J.-J. Cherng, W.-S. Sheu, G.-A. Lee and M. Shieh,* “Novel Types of Organic S-Fe-CO Complexes: Reaction of [SFe3(CO)9]2- with Propargyl Bromide,” Organometallics 2006, 25, 184. [10.1021/om050694q]
    29.  M. Shieh,* S.-F. Lin, Y.-W. Guo, M.-H. Hsu and Y.-W. Lai, “New Strategy to Mixed-Group 6 Metal Carbonyl Telluride Complexes: Completion of the Trigonal Bipyramidal Clusters [Te2CrM2(CO)10]2- (M = Cr, Mo, W),” Organometallics 2004, 23, 5182. [10.1021/om049515f]
    30. M. Shieh,* H.-S. Chen and Y.-W. Lai, “Reaction of the Tellurium-Capped Triiron Cluster [TeFe3(CO)9]2- with the Bifunctional Propargyl Bromide: Formation of a Series of Novel Organic Te-Fe-CO Complexes,” Organometallics 2004, 23, 4018. [10.1021/om049712e]
    31. M. Shieh,* R.-L. Chung, C.-H. Yu, M.-H Hsu, C.-H. Ho, S.-M. Peng and Y.-H. Liu, “The Unusual Paramagnetic Mixed-Metal Carbonyl Chalcogenide Clusters: [E2Cr2Fe(CO)10]2- (E = Te, Se),” Inorg. Chem. 2003, 42, 5477. [10.1021/ic034081m]
    32. M. Shieh,* L.-F. Ho, Y.-W. Guo, S.-F. Lin, Y.-C. Lin, S.-M. Peng and Y.-H. Liu, “Carbonylchromium Monotelluride Complexes [Et4N]2[Te{Cr(CO)5}n] (n = 2, 3): Two Important Intermediates,” Organometallics 2003, 22, 5020. [10.1021/om034033+]
    33. M. Shieh,* Y. Liou, M.-H. Hsu, R.-T. Chen, S.-J. Yeh, S.-M. Peng and G.-H. Lee, “A Unique Bismuth-Iron Chain Polymer Containing the ...-Bi-Fe-... Link: Formation and Structure of [n-BuBiFe(CO)4]¥,”  Angew. Chem. Int. Ed. Engl. 2002, 41, 2384; Angew. Chem. 2002, 114, 2490. [https://doi.org/10.1002/1521-3773(20020703)41:13<2384::AID-ANIE2384>3.0.CO;2-%23]
    34. M. Shieh,* J.-J. Cherng, Y.-W. Lai, S.-M. Peng and Y.-H. Liu, “Carbonylchromium Derivatives of Bismuth: New Syntheses and Relevance to C-O Activation,” Chem. Eur. J. 2002, 8, 4522. [10.1002/1521-3765(20021004)8:19<4522::AID-CHEM4522>3.0.CO;2-7]
    35. J.-J. Cherng, Y.-W. Lai, Y.-H. Liu, S.-M. Peng, C.-H. Ueng and M. Shieh,* “Synthesis of Chromium Pentacarbonyl Dertives of Arsenic(V) and Antimony(V). Contrasting Chemical Reactivity with Organic Halogen Derivatives,” Inorg. Chem. 2001, 40, 1206. [10.1021/ic0004277]
    36. M. Shieh,* H.-S. Chen, H.-Y. Yang, S.-F. Lin and C.-H. Ueng, “Tellurium-Bridged Manganese Carbonyl Clusters: Synthesis and Structural Transformations of [Te4Mn3(CO)10]-, [Te2Mn3(CO)9]2-, [Te2Mn3(CO)9]-, and [Te2Mn4(CO)12]2-,” Chem. Eur. J. 2001, 7, 3152. [10.1002/1521-3765(20010716)7:14<3152::AID-CHEM3152>3.0.CO;2-B]
    37. M. Shieh,* L.-F. Ho, L.-F. Jang, C.-H. Ueng, S.-M. Peng and Y.-H. Liu, “First Selenium-Capped Carbonyltrichromium Complex [Se2Cr3(CO)10]2-: a Novel Cr3 Ring Cluster,” Chem. Commun. 2001, 1014. [10.1039/b101283p]
    38. M. Shieh,* H.-S. Chen, H.-H Chi and C.-H. Ueng, “Synthesis of an Se-Bridged Triiron Acyl Cluster Complex and the Fischer-Type Carbene Complex Derived from It: Isolation of Rotation Isomers,” Inorg. Chem. 2000, 39, 5561. [10.1021/ic000301+]
    39. J.-J. Cherng, G.-H. Lee, S.-M. Peng, C.-H. Ueng and M. Shieh,* “Synthesis and Characterization of a New Series of Chromium-Group 15 Hydride Complexes [Et4N]2[H{Cr(CO)5}3]) (E = As, Sb),” Organometallics 2000, 19, 213. [10.1021/om990717z]
    40. M. Shieh,* H.-S. Chen, Y.-H Yang and C.-H. Ueng, “[Mn(CO)4TeMe2(μ5-Te)(μ4-Te)Mn4(CO)12]- : A Pentacoordinate Bridging Tellurido Ligand in a Square Pyramidal Geometry,” Angew. Chem. Int. Ed. Engl. 1999, 38, 1252. [10.1002/(SICI)1521-3773(19990503)38:9<1252::AID-ANIE1252>3.0.CO;2-A