林文伟
姓名 林文伟
电子邮件
联络电话 (02)77496131
网站 http://140.122.142.231/~wwlin/index.htm
实验室电话 (02)77496200
职称 优聘教授
研究领域
  • 不对称有机催化反应的开发
  • 新颖合成反应的开发
  • 杂环化学合成、有机合成
学术专长 不对称有机催化、有机磷诱导或催化反应、杂环化学合成、有机金属。
指导学生 博士后研究员: Dr. 陈奕儒, Dr.  Gangababu Marri。
博士班: 吴佩珊, Durga Prasad Gurram, Raghunath Maruti Walunj, Ganesh Shantaram Khomane, Naveen Jothimani。
硕士班: 刘家庆, 施承均, 陈佑杰, 陈彦恺, 陈俞瑄, 潘柏瑄, 陈沂祯, 馀如音, 张嘉讌。

 
实验室 有机实验室  / 有机不对称催化和杂环化学研究实验室
  1. Chien, P.-C.; Chen, Y.-J.; Marri, G.; Chen, Y.-R.; Chang, C.-F.; Lin, W.* "Syntheses of β-Acylated Alkylidene Indandiones and Furo[2,3-f]dibenzotropones via MBH-type Annulation/acylation or Wittig Reaction" J. Chin. Chem. Soc. 2024, accepted.
  2. Gurram, P. D.; Marri, G.; Jothimani, N.; Lin, W.* "Diversity-Oriented Synthesis of Chromone Inden-1-one Fused Cyclopentadienylides and C-Acylated Chromone Adducts via Allylic Phosphorus Ylides" Chem. Commun. 2024, 60, 9817-9820.参考连结
  3. Chen, Y.-R.; Marri, G.; Lin, W.* "The Integral Role of Conjugate Acids in Brønsted Base-Catalyzed Regiodivergent Synthesis" ChemCatChem 2024, 16, e202400405.参考连结
  4. Chien, P.-C.; Chen, Y.-R.; Chen, Y.-J.; Chang, C.-F.; Marri, G.; Lin, W.* "Synthesis of Furo[2,3-f]dibenzotropones via Intramolecular Wittig Reaction of Alkylidene Dibenzo-β-tropolones" Adv. Synth. Catal. 2024, 366, 420-425.参考连结
  5. Liou, Y.-C.; Chen, Y.-R.; Hsu, C.-W.; Huang, X.-R.; Wang, H.-W.; Lin, W.* "Alkylidene Meldrum's Acid as Acceptor-Donor-Acceptor Substrate for Organocatalytic Asymmetric (3+2) Cycloaddition/Annulation Reaction" Adv. Synth. Catal. 2023, 365, 3603-3610.参考连结
  6. Wu, P.-S.; Liou, Y.-C.; Marri, G.; Chen, Y.-R.; Wu, J.-R.; Lin, W.* "Synthesis of Chromeno[4,3-b]pyrrolidines from Azomethine Ylides and Vinyl para-Quinone Methides via (3+2) Cycloaddition/oxa-1,6-addition" J. Chin. Chem. Soc. 2023, 70, 2136-2146.参考连结
  7. Lung, T.-H.; Chen, Y.-R.; Chang, C.-L.; Jeng, W.-C.; Wu, P.-S.; Vagh, S.; Marri, G.; Lin, Y.-F.; Lin, W.* "Diversity-Oriented Synthesis of Spiro- and 3-Methylene-hydroquinone-Indandiones via an Organobase-Controlled Cascade Strategy" Adv. Synth. Catal. 2023, 365, 1391-1397.参考连结
  8. Vagh, S.; Hou, B.-J.; Edukondalu, A.; Wang, P.-C.; Chen, Y.-R.; Lin, W.* "Phosphine-Mediated Rauhut-Currier-Type/Acyl Transfer/ Wittig Strategy for Synthesis of Spirocyclopenta[c]chromene-Indolinones" Adv. Synth. Catal. 2021, 363, 5429-5435.参考连结
  9. Khairnar, P.; Su, Y.-H.; Edukondalu, A.; Lin, W.* "Enantioselective Synthesis of Spiropyrazolone-Fused Cyclopenta[c]chromen-4-ones Bearing Five Contiguous Stereocenters via (3+2) Cycloaddition" J. Org. Chem. 2021, 86, 12326-12335. 参考连结
  10. Jeng, W.-C.; Chien, P.-C.; Vagh, S.; Edukondalu, A.; Lin, W.* "Organophosphane-Catalyzed Construction of Functionalized 2-Ylideneoxindoles via Direct β-Acylation" Synthesis 2021, 53, 4409-4418. 参考连结
  11. Liou, Y.-C.; Wang, H.-W.; Edukondalu, A.; Lin, W.* "Phosphine-Catalyzed Chemoselective Reduction/Elimination/Wittig Sequence for Synthesis of Functionalized 3-Alkenyl Benzofurans" Org. Lett. 2021, 23, 3064-3069.参考连结
     
  12. Edukondalu, A.; Vagh, S.; Lin, T.-H.; Lin, W.* "Construction of Indeno[1,2-b]pyrroles via Chemoselective N‒Acylation/Cyclization/Wittig Reaction Sequence" Chem. Commun. 2021, 57, 2045-2048.参考连结
  13. Vagh, S.; Hou, B.-J.; Edukondalu, A.; Wang, P.-C.; Lin, W.* "Phosphine-Mediated MBH-Type/Acyl Transfer/Wittig Sequence for Construction of Functionalized Furo[3,2-c]coumarins" Org. Lett. 2021, 23, 842-846.参考连结
  14. Huang, C.-C.; Chang, K.-H.; Chiu, Y.-J.; Chen, Y.-R.; Lung, T.-H.; Hsieh-Li, H.-M.; Su, M.-T.; Sun, Y.-C.; Chen, C.-M.*; Lin, W.*; Lee-Chen, G.-J.* "Multi-target effects of novel synthetic coumarin derivatives protecting Aβ-GFP SH-SY5Y cells against Aβ Toxicity" Cells 2021, 10, 3095.参考连结
  15. Chiu, Y.-J.; Lin, T.-H.; Chen, C.-M.; Lin, C.-H.; Teng, Y.-S.; Lin, C.-Y.; Sun, Y.-C.; Hsieh-Li, H.-M.; Su, M.-T.; Lee-Chen, G.-J.*; Lin, W.*; Chang, K.-H.* "Novel Synthetic Coumarin-Chalcone Derivative (E)-3-(3-(4-(Dimethylamino)Phenyl)Acryloyl)-4-Hydroxy-2H-Chromen-2-One Activates CREB-Mediated Neuroprotection in Aβ and Tau Cell Models of Alzheimer's Disease" Oxid. Med. Cell. Longev. 2021, 2021, 3058861. 参考连结
  16. Khairnar, P.; Su, Y.-H.; Chen, Y.-C.; Edukondalu, A.; Chen, Y.-R.; Lin, W.* "Organophosphane-Catalyzed Direct β-Acylation of 4-Arylidene Pyrazolones and 5-Arylidene Thiazolones with Acyl Chlorides" Org. Lett. 2020, 22, 6868-6872.参考连结
  17. Wang, M.; Tseng, P.-Y.; Chi, W.-J.; Suresh, S.; Edukondalu, A.; Chen, Y.-R.; Lin, W.* "Diversity-Oriented Synthesis of Spirocyclohexene Indane-1,3-diones and Coumarin-Fused Cyclopentanes via an Organobase-Controlled Cascade Reaction" Adv. Synth. Catal. 2020, 362, 3407-3415. 参考连结
  18. Khairnar, P.; Wu, C.-Y.; Lin, Y.-F.; Edukondalu, A. Chen, Y.-R.; Lin, W.* "Diversity-Oriented Synthesis of Spiropentadiene Pyrazolones and 1-H-Oxepino[2,3-c]pyrazoles from Doubly Conjugated Pyrazolones via Intramolecular Wittig Reaction" Org. Lett. 2020, 22, 4760-4765. 参考连结
  19. Vagh, S. S.; Karanam, P.; Liao, C.-C.; Lin, T.-H.; Liou, Y.-C.; Edukondalu, A.; Chen, Y.-R.; Lin, W.* "Enantioselective Construction of Spirooxindole-Fused Cyclopenta[c]chromen-4-ones Bearing Five Contiguous Stereocenters via a Stepwise (3+2) Cycloaddition" Adv. Synth. Catal. 2020, 362, 1679-1685. 
     
     参考连结
  20. Liou, Y.-C.; Su, Y.-H.; Ku, K.-C.; Edukondalu, A.; Lin, C.-K.; Ke, Y.-S.; Karanam, P.; Lee, C.-J.; Lin, W.* "Organophosphane-Promoted Synthesis of Functionalized α,β-Unsaturated Alkenes and Furanones via Direct β-Acylation" Org. Lett. 2019, 21, 8339-8343.
     
     参考连结
  21. Liou, Y.-C.; Karanam, P.; Jang, Y.-J.; Lin, W.* "Synthesis of Functionalized Benzofurans from para-Quinone Methides via Phospha-1,6-Addition/O-acylation/Wittig Pathway" Org. Lett. 2019, 21, 8008-8012. 参考连结
  22. Khairnar, P.; Lung, T.-H.; Lin, Y.-J.; Wu, C.-Y.; Koppolu, S.; Edukondalu, A.; Karanam, P.; Lin, W.* "An Intramolecular Wittig Approach toward Heteroarenes: Synthesis of Pyrazoles, Isoxazoles, and Chromenone-oximes" Org. Lett. 2019, 21, 4219-4223. 
     
     参考连结
  23. Yang, S.-M.; Karanam, P.; Wang, M.; Jang, Y.-J.; Yeh, Y.-S.; Tseng, P.-Y.; Reddy, G. M.; Liou, Y.-C.; Lin, W.* "A Vinylogous Michael Addition-Triggered Quadruple Cascade Reaction for the Enantioselective Generation of Multiple Quaternary Stereocenters" Chem. Commun. 2019, 55, 1398-1401. 参考连结
  24. Karanam, P.; Reddy, G. M.; Lin, W.* "Strategic Exploitation of Wittig Reaction: Facile Synthesis of Heteroaromatics and Multifunctional Olefins" Synlett 2018, 29, 2608-2622. 参考连结
  25. Lee, S.-Y.; Chiu, Y.-J.; Yang, S.-M.; Chen, C.-M.; Huang, C.-C.; Lee-Chen, G.-J.*; Lin, W.*; Chang, K.-H.* "Novel Synthetic Chalcone–coumarin Hybrid for Aβ Aggregation Reduction, Antioxidation, and Neuroprotection" CNS Neurosci. Ther. 2018, 24, 1286-1298. 参考连结
  26. Chen, Y.-R.; Reddy, G. M.; Hsieh, K.-H.; Chen, K.-H.; Karanam, P.; Vagh, S. S.; Liou, Y.-C.; Lin, W.* "3-Homoacyl coumarin: an all carbon 1,3-dipole for enantioselective concerted (3+2) cycloaddition" Chem. Commun. 2018, 54, 12702-12705. 参考连结
  27. Yu, J.-K.; Chien, H.-W.; Lin, Y.-J.; Karanam, P.; Chen, Y.-H.; Lin, W.* "Diversity-oriented synthesis of chromenopyrrolidines from azomethine ylides and 2-hydroxybenzylidene indandiones via base-controlled regiodivergent (3+2) cycloaddition" Chem. Commun. 2018, 54, 9921-9924. 参考连结
  28. Yang, S.-M.; Wang, C.-Y.; Lin, C.-K.; Karanam, P.; Reddy, G. M.; Tsai, Y.-L.; Lin, W.* "Diversity-Oriented Synthesis of Furo[3,2-c]coumarins and Benzofuranyl Chromenones via Chemoselective Acylation/Wittig Reaction" Angew. Chem. Int. Ed. 2018, 57, 1668-1672; Angew. Chem. 2018, 130, 1684-1688. 参考连结
  29. Karanam, P.; Reddy, G. M.; Koppolu, S. R.; Lin, W.* "Recent topics of phosphine-mediated reactions" Tetrahedron Lett. 2018, 59, 59-76. 参考连结
  30. Yang, S.-M.; Tsai, Y.-L.; Reddy, G. M.; Moehlmann, L.; Lin, W.* "Chemo- and diastereoselective Michael-Michael-acetalization cascade for the synthesis of 1,3-indandione-fused spiro[4.5]decan scaffolds" J. Org. Chem. 2017, 82, 9182-9190. 参考连结
  31. Yang, S.-M.; Reddy, G. M.; Wang, T.-P.; Yeh, Y.-S.; Wang, M.; Lin, W.* "An Enantioselective Cascade for Simultaneous Generation of Five Quaternary Stereocenters from Fully Substituted Enones" Chem. Commun. 2017, 53, 7649-7652. 参考连结
  32. Chen, Y.-R.; Reddy, G. M.; Hong, S.-H.; Wang, Y.-Z.; Yu, J.-K.; Lin, W.* "Four-component synthesis of phosphonium salts: application toward an alternative approach to cross-coupling for the synthesis of bis-heteroarenes" Angew. Chem. Int. Ed. 2017, 56, 5106-5110; Angew. Chem. 2017, 129, 5188-5192.  参考连结
  33. Yang, S.-M.; Reddy, G. M.; Liu, M.-H.; Wang, T.-P.; Yu, J.-K.; Lin, W.* "Diastereoselective Synthesis of Rauhut-Currier-Type Adducts via An Unexpected α-Addition of α,β-Unsaturated r-Butyrolactams to Coumarin Derivatives" J. Org. Chem. 2017, 82, 781-789. 参考连结
  34. Chang, G.-H.; Wang, C.-Y.; Reddy, G. M.; Tsai, Y.-L.; Lin, W.* "Enantioselective synthesis of polysubstituted benzopyrano[3,4-c]pyrrolidine frameworks via [3+2] cycloaddition of azomethine ylides and coumarin derivatives" J. Org. Chem. 2016, 81, 10071-10080. 参考连结
  35. Lee, C.-J.; Chang, T.-H.; Yu, J.-K.; Reddy, G. M.; Hsiao, M.-Y.; Lin, W.* "Synthesis of functionalized furans via chemoselective reduction/Wittig reaction using catalytic triethylamine and phosphine" Org. Lett. 2016, 18, 3758-3761. 参考连结
  36. Reddy, G. M.; Ko, C.-T.; Hsieh, K.-H.; Lee, C.-J.; Das, U.; Lin, W.* "Expanding the scope of primary amine catalysis: Highly stereoselective synthesis of indanedione-fused 2,6-disubstituted trans-spirocyclohexanones" J. Org. Chem. 2016, 81, 2420-2431. 参考连结
  37. Moehlmann, L.; Chang, G.-H.; Reddy, G. M.; Lee, C.-J.; Lin, W.* "Organocatalytic enantioselective synthesis of tetrahydrofluoren-9-ones via vinylogous Michael addition/Henry reaction cascade of 1,3-indandione-derived pronucleophiles" Org. Lett. 2016, 18, 688-691. 参考连结
  38. Lee, C.-J.; Tsai, C.-C.; Hong, S.-H.; Chang, G.-H.; Yang, M.-C.; Moehlmann, L.; Lin, W.* "Preparation of Furo[3,2-c]coumarins from 3-Cinnamoyl-4-hydroxy-2H-chromen-2-ones and Acyl Chlorides: A Bu3P-Mediated C-Acylation/Cyclization Sequence" Angew. Chem. Int. Ed. 2015, 54, 8502-8505; Angew. Chem. 2015, 127, 8622-8625. 参考连结
  39. Tsai, Y.-L.;  Lin, W.* "Synthesis of multifunctional alkenes from substituted acrylates and aldehydes via phosphine-catalyzed Wittig reaction" Asian J. Org. Chem. 2015, 4, 1040-1043. 参考连结
  40. Chen, C.-H.; Ko, C.-T.; Reddy, G. M.; Lee, C.-J.; Lin, W.* "An enantioselective synthesis of substituted cyclohexanone derivatives with an all-carbon quaternary stereocenter by using an organocatalytic asymmetric domino double Michael addition" Eur. J. Org. Chem. 2015, 5254-5265. 参考连结
  41. Jang, Y.-J.; Chen, Y.-S.; Lee, C.-J.; Chen, C.-H.; Reddy G. M.; Ko, C.-T.; Lin, W.* "Asymmetric organocatalytic synthesis of highly substituted cyclohexenols via domino double Michael reactions of 1-hydroxy-1,4-dien-3-ones and 2-alkylidene malononitirles" Eur. J. Org. Chem. 2015, 2066-2074. 参考连结
  42. Chen, Y.-R.; Das, U.; Liu, M.-S.; Lin, W.* "Organocatalytic Enantioselective Direct Vinylogous Michael Addition of alpha,belta-Unsaturated gamma-Butyrolactam to belta-Acyl Acrylates and 1,2-Diacylethylenes” J. Org. Chem. 2015, 80, 1985-1992. 参考连结
  43. Jang, Y.-J.; Chen, Y.-S.; Lee, C.-J.; Chen, C.-H.; Lin, W.* "Base-Catalyzed Domino Double Michael Reactions of 1-Hydroxy-1,4-dien-3-ones and 2-Alkylidene Malononitirles: A Diastereoselective Route to Polysubstituted 4-Hydroxy-3-keto-cyclohex-3-ene” Synthesis 2015, 47, 95-107. 参考连结
  44. Fan, Y.-S.; Das, U.; Hsiao, M.-Y.; Liu, M.-S.; Lin, W.* "Chemoselective Intramolecular Wittig Reactions for the Synthesis of Oxazoles and Benzofurans” J. Org. Chem. 2014, 79, 11567-11582. 参考连结
  45. Das, U.; Tsai, Y.-L.; Lin, W.* "Preparation of functionalized heteroaromatics using intramolecular Wittig reaction" Org. Biomol. Chem. 2014, 12, 4044-4050. (Perspective) (This article is part of the themed collection: 2014 Hot Articles in Organic and Biomolecular Chemistry) 参考连结
  46. Tsai, Y.-L.; Syu, S.; Yang, S.-M.; Das, U.; Fan, Y.-S.; Lee, C.-J.; Lin, W.* "Synthesis of Multi-Functional Alkenes via Wittig Reaction with a New-Type of Phosphorus Ylides” Tetrahedron 2014, 70, 5038-5045. 参考连结
  47. Lee, C.-J.; Sheu, C.-N.; Tsai, C.-C.; Wu, Z.-Z.; Lin, W.* "Direct  β-Acylation of 2-Arylidene-1,3-indandiones with Acyl Chlorides Catalyzed by Organophosphanes” Chem. Commun. 2014, 50, 5304-5306.(Featured in "Emerging investigators" issue 2014) 参考连结
  48. "Contributors to the Emerging Investigators Issue 2014", Chem. Commun. 2014, 50, 5100-5114. 参考连结
  49. Lee, Y.-T.; Das, U.; Chen, Y.-R.; Lee, C.-J.; Chen, C.-H.; Yang, M.-C.; Lin, W.* "Enantioselective Synthesis of Coumarin Derivatives Catalyzed by Primary Amine" Adv. Synth. Catal. 2013, 355, 3154-3160. 参考连结
  50. Tsai, Y.-L.; Fan, Y.-S.; Lee, C.-J.; Huang, C.-H.; Das, U.; Lin, W.* "An Efficient Synthesis of Trisubstituted Oxazoles via Chemoselective O-Acylations and Intramolecular Wittig Reactions" Chem. Commun. 2013, 49, 10266-10268. 参考连结
  51. Lee, Y.-T.; Lee, Y.-T.; Lee, C.-J.; Sheu, C.-N.; Lin, B.-Y.; Wang, J.-H.*; Lin, W.* "Chemoselective Synthesis of Tetrasubstituted Furans via Intramolecular Wittig Reactions: Mechanism and Theoretical Analysis" Org. Biomol. Chem. 2013, 11, 5156-5161. 参考连结
  52. Tsai, Y.-L.; Das, U.; Syu, S.; Lee, C.-J.; Lin, W.* "Facile synthesis of functional tricyclic fused furans via intramolecular Wittig reactions" Eur. J. Org. Chem. 2013, 4634-4641. 参考连结
  53. Das, U.; Chen, Y.-R.; Tsai, Y.-L.; Lin, W.* "Organocatalytic enantioselective direct vinylogous Michael addition of r-substituted butenolides to 3-aroyl acrylates and 1,2-diaroylethylenes"Chem. Eur. J. 2013, 19, 7713-7717. 参考连结
  54. Wu, Z.-Z.; Jang, Y.-J.; Lee, C.-J.; Lee, Y.-T.; Lin, W.* "A Versatile and Practical Method for Regioselective Synthesis of Polysubstituted Furanonaphthoquinones" Org. Biomol. Chem. 2013, 11, 828-834. (HOT article) 参考连结
  55. Das, U.; Tsai, Y.-L.; Lin, W.* "An efficient organocatalytic enantioselective synthesis of spironitrocyclopropanes" Org. Biomol. Chem. 2013, 11, 44-47. (HOT communication) 参考连结
  56. Lee, Y.-T.; Jang, Y.-J.; Syu, S.; Chou, S.-C.; Lee, C.-J.; Lin, W.* “Preparation of Functional Benzofurans and Indoles via Chemoselective Intramolecular Wittig Reactions" Chem. Commun. 2012, 48, 8135-8137. 参考连结
  57. Das, U.; Huang, C.-H.; Lin, W.* "Enantioselective synthesis of substituted pyrans via amine-catalyzed Michael addition and subsequent enolization/cyclisation" Chem. Commun. 2012, 48, 5590-5592. (Featured in "Organocatalysis" Web-themed issue) 参考连结
  58. Lee, C.-J.; Jang, Y.-J.; Wu, Z.-Z. ; Lin, W.* "Preparation of Functional Phosphorus Zwitterions from Activated Alkanes, Aldehydes, and Tributylphosphine: Synthesis of Polysubstituted Furo[3,2-c]coumarins" Org. Lett. 2012, 14, 1906-1909. 参考连结
  59. Jang, Y.-J.; Syu, S.; Jhang, Y.-W.; Lee, Y.-T.; Lee, C.-J.; Chen, K.-W.; Das, U.; Lin, W.* "Tandem three-component reactions of aldehyde, alkyl acrylate, and dialkylmalonate catalyzed by ethyl diphenylphosphine" Molecules 2012, 17, 2529-2541. 参考连结
  60. Syu, S.; Huang, C.-H.; Chen, K.-W.; Lee, C.-J.; Das, U.; Jang, Y.-J.; Lin, W.* "Enantioselective organocatalytic Michael addition of ketones to alkylidene malonates"Chirality 2012, 24, 600-605. 参考连结
  61. Jang, Y.-J.; Syu, S.; Chen, Y.-J.; Yang, M.-C.; Lin, W.* "Syntheses of Furo[3,4-c]coumarins and Related Furyl Coumarin Derivatives via Intramolecular Wittig Reactions" Org. Biomol. Chem. 2012, 10, 843-847. 参考连结
  62. Syu, S.; Lee, Y.-T.; Jang, Y.-J.; Lin, W.* "Preparation of Functional Benzofurans, Benzothiophenes, and Indoles Using Ester, Thioester, and Amide via Intramolecular Wittig Reactions" Org. Lett. 2011, 13, 2970-2973. 参考连结
  63. Syu, S.; Lee, Y.-T.; Jang, Y.-J.; Lin, W.* "Organocatalytic tandem three-component reaction of imine, alkyl vinyl ketone, and imide via aza-Baylis-Hillman reaction" J. Org. Chem. 2011, 76, 2888-2891. 参考连结
  64. Chen, K.-W.; Syu, S.; Jang, Y.-J.; Lin, W.* "A facile approach to highly functional trisubstituted furans via intramolecular Wittig reactions"Org. Biomol. Chem. 2011, 9, 2098-2106. 参考连结
  65. Wang, D.-W.; Syu, S.; Hung, Y.-T.; Chen, P.; Lee, C. J.; Chen, K.-W.; Chen, Y.-J.; Lin, W.* "Organocatalytic Tandem Three-Component Reaction of Aldehyde, Alkyl Vinyl Ketone, and Amide: One-Pot Syntheses of Highly Functional Alkenes"Org. Biomol. Chem. 2011, 9, 363-366. 参考连结
  66. Syu, S.; Wang, D.-W.; Chen, P.; Hung, Y.-T.; Jhang, Y.-W.; Kao, T.-T.; Lee, Y.-T.; Lin, W.* "Tandem Three-Component Reaction of Aldehyde, Alkyl Acrylate and Amide Using Ethyl Diphenylphosphine as Organocatalyst" Tetrahedron Lett. 2010, 51, 5943-5946.
    参考连结
  67. Kao, T.-T.; Syu, S.; Jhang, Y.-W.; Lin, W.* "Preparation of Tetrasubstituted Furans via Intramolecular Wittig Reactions with Phosphorus Ylides as Intermediates", Org. Lett. 2010, 12, 3066-3069. 参考连结
  68. Syu, S.; Kao, T.-T.; Lin, W.* "A New Type of Organocatalyst for Highly Stereoselective Michael Addition of Ketones to Nitroolefins on Water", Tetrahedron 2010, 66, 891–897. 参考连结
  69. Lin, W.; Chen, L.; Knochel, P.* "Preparation of Functionalized 3,4-Pyridynes via 2-Magnesiated Diaryl Sulfonates", Tetrahedron 2007, 63, 2787-2797.
  70. Lin, W.; Ilgen, F.; Knochel, P.* "Preparation of Highly Functionalized Arylmagnesium Reagents by the Addition of Magnesium Phenylselenide to Arynes", Tetrahedron Lett. 2006, 47, 1941-1944.
  71. Lin, W.; Baron, O.; Knochel, P.* "Highly Functionalized Benzene Syntheses by Directed Mono or Multiple Magnesiations with TMPMgCl‧LiCl", Org. Lett. 2006, 8, 5673-5676.
  72. Sapountzis, I.; Lin, W.; Kofink, C. C.; Despotopoulou, C.; Knochel, P.* "Iron-Catalyzed Aryl-Aryl Cross-Couplings with Magnesium-Derived Copper Reagents", Angew. Chem. Int. Ed. 2005, 44, 1654-1657. Angew. Chem. 2005, 117, 1682-1685.
  73. Lin, W.; Sapountzis, I.; Knochel, P.* "Preparation of Functionalized Aryl Magnesium Reagents by the Addition of Magnesium Aryl Thiolates and Amides to Arynes", Angew. Chem. Int. Ed. 2005, 44, 4258-4261. Angew. Chem. 2005, 117, 4330-4333.
  74. Sapountzis, I.; Lin, W.; Fischer, M.; Knochel, P.* "Preparation of Polyfunctional Arynes via 2-Magnesiated Diaryl sulfonates", Angew. Chem. Int. Ed. 2004, 43, 4364-4366. Angew. Chem. 2004, 116, 4464-4466.
  75. Jang, Y.-J.; Lin, W.-W.; Shih, Y.-K.; Liu, J.-T.; Hwang, M.-H.; Yao, C.-F.* "An Easy One-Pot Method for the Synthesis of 2,2-Disubstituted 1-Nitroalkenes", Tetrahedron 2003, 59, 4979-4992.
  76. Lin, W.-W.; Jang, Y.-J.; Wang, Y.; Liu, J.-T.; Hu, S.-R.; Wang, L.-Y.; Yao, C.-F.* "An Improved and Easy Method for the Preparation of 2,2-Disubstituted 1-Nitroalkenes", J. Org. Chem. 2001, 66, 1984-1991.
  77. Liu, J.-T; Lin, W.-W.; Jang, J.-J.; Liu, J.-Y.; Yan, M.-C.; Hung, C.; Kao, K.-H.; Wang, Y.; Yao, C.-F.* "One-pot synthesis of six- or five-membered carbocycles through intramolecular cycloadditions by the use of ethyl chloroformate", Tetrahedron 1999, 55, 7115-7128.
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年度 论文名称
2023 Synthesis of Chromeno[4,3-b]pyrrolidines from Azomethine Ylides and Vinyl para-Quinone Methides via (3+2) Cycloaddi-tion/oxa-1,6-addition, Journal of the Chinese Chemical Society, vol. 70, Dec. 2023
2023 Alkylidene Meldrum's Acid as Acceptor-Donor-Acceptor Sub-strate for Organocatalytic Asymmetric (3+2) Cycloaddi-tion/Annulation Reaction, Advanced Synthesis & Catalysis, vol. 365, Nov. 2023
2023 Diversity-Oriented Synthesis of Spiro- and 3-Methylene-hydroquinone-Indandiones via an Organobase-Controlled Cascade Strategy, Advanced Synthesis & Catalysis, vol. 365, May. 2023
2021 Organophosphane-Catalyzed Construction of Functionalized 2-Ylideneoxindoles via Direct β-Acylation, Synthesis-Stuttgart, vol. 53, Dec. 2021
2021 Phosphine-Mediated Rauhut-Currier-Type/Acyl Transfer/Wittig Strategy for Synthesis of Spirocyclopenta[c]chromene-Indolinones, Advanced Synthesis & Catalysis, vol. 363, Dec. 2021
2021 Enantioselective Synthesis of Spiropyrazolone-Fused Cyclopenta[c]chromen-4-ones Bearing Five Contiguous Stereocenters via (3+2) Cycloaddition, The Journal of Organic Chemistry, vol. 86, Sep. 2021
2021 Phosphine-Catalyzed Chemoselective Reduction/Elimination/Wittig Sequence for Synthesis of Functionalized 3-Alkenyl Benzofurans, Organic Letters, vol. 23, Apr. 2021
2021 Phosphine-Mediated MBH-Type/Acyl Transfer/Wittig Sequence for Construction of Functionalized Furo[3,2-c]coumarins, Organic Letters, vol. 23, Feb. 2021
2021 Construction of Indeno[1,2-b]pyrroles via Chemoselective N‒Acylation/Cyclization/Wittig Reaction Sequence, Chemical Communications, vol. 57, Feb. 2021
2020 Organophosphane-Catalyzed Direct β-Acylation of 4-Arylidene Pyrazolones and 5-Arylidene Thiazolones with Acyl Chlorides, Organic Letters, vol. 22, Sep. 2020
2020 Diversity-Oriented Synthesis of Spirocyclohexene Indane-1,3-diones and Coumarin-Fused Cyclopentanes via an Organobase-Controlled Cascade Reaction, Advanced Synthesis & Catalysis, vol. 362, Aug. 2020
2020 Diversity-Oriented Synthesis of Spiropentadiene Pyrazolones and 1-H-Oxepino[2,3-c]pyrazoles from Doubly Conjugated Pyrazolones via Intramolecular Wittig Reaction, Organic Letters, vol. 22, Jun. 2020
2020 Enantioselective Construction of Spirooxindole-Fused Cyclopenta[c]chromen-4-ones Bearing Five Contiguous Stereocenters via a Stepwise (3+2) Cycloaddition, Advanced Synthesis & Catalysis, vol. 362, Apr. 2020
2019 Organophosphane-Promoted Synthesis of Functionalized α,β-Unsaturated Alkenes and Furanones via Direct β-Acylation, Organic Letters, vol. 21, Oct. 2019
2019 Synthesis of Functionalized Benzofurans from para-Quinone Methides via Phospha-1,6-Addition/O-acylation/Wittig Pathway, Organic Letters, vol. 21, Sep. 2019
2019 An Intramolecular Wittig Approach toward Heteroarenes: Synthesis of Pyrazoles, Isoxazoles, and Chromenone-oximes, Organic Letters, vol. 21, Jun. 2019
2019 A vinylogous Michael addition-triggered quadruple cascade reaction for the enantioselective generation of multiple quaternary stereocenters, Chemical Communications, vol. 55, Feb. 2019
2018 Strategic Exploitation of Wittig Reaction: Facile Synthesis of Heteroaromatics and Multifunctional Olefins, Synlett, vol. 29, Dec. 2018
2018 Novel Synthetic Chalcone–coumarin Hybrid for Aβ Aggregation Reduction, Antioxidation, and Neuroprotection, CNS Neuroscience & Therapeutics, vol. 24, Dec. 2018
2018 3-Homoacyl coumarin: an all carbon 1,3-dipole for enantioselective concerted (3+2) cycloaddition, Chemical Communications, vol. 54, Nov. 2018
2018 Diversity-oriented synthesis of chromenopyrrolidines from azomethine ylides and 2-hydroxybenzylidene indandiones via base-controlled regiodivergent (3+2) cycloaddition, Chemical Communications, vol. 54, Sep. 2018
2018 Diversity-Oriented Synthesis of Furo[3,2-c]coumarins and Benzofuranyl Chromenones via Chemoselective Acylation/Wittig Reaction, Angewandte Chemie International Edition, vol. 57, Feb. 2018
2018 Recent topics of phosphine-mediated reactions, Tetrahedron Letters, vol. 59, Jan. 2018
2017 Chemo- and diastereoselective Michael-Michael-acetalization cascade for the synthesis of 1,3-indandione-fused spiro[4.5]decan scanffolds, The Journal of Organic Chemistry, vol. 82, Sep. 2017
2017 An Enantioselective Cascade for Simultaneous Generation of Five Quartenary Stereocenters from Fully Substituted Enones, Chemical Communicatons, vol. 53, Jul. 2017
2017 Four-component synthesis of phosphonium salts: application toward an alternative approach to cross-coupling for the synthesis of bis-heteroarenes, Angewandte Chemie International Edition, vol. 56, Apr. 2017
2017 Diastereoselective Synthesis of Rauhut-Currier-Type Adducts via An Unexpected alpha,beta-Unsaturated gamma-Butyrolactams to Coumarin Derivatives, The Journal of Organic Chemistry, vol. 82, Jan. 2017
2016 Enantioselective synthesis of polysubstituted benzopyrano[3,4-c]pyrrolidine frameworks via [3+2] cycloaddition of azomethine ylides and coumarin derivatives, The Journal of Organic Chemistry, vol. 81, Oct. 2016
2016 Synthesis of functionalized furans via chemoselective reduction/Wittig reaction using catalytic triethylamine and phosphine, Organic Letters, vol. 18, Aug. 2016
2016 Expanding the Scope of Primary Amine Catalysis: Stereoselective Synthesis of Indanedione-Fused 2,6-Disubstituted trans-Spirocyclohexanones, The Journal of Organic Chemistry, vol. 81, Mar. 2016
2016 Organocatalytic Enantioselective Synthesis of Tetrahydrofluoren-9-ones via Vinylogous Michael Addition/Henry Reaction Cascade of 1,3-Indandione-Derived Pronucleophiles, Organic Letters, vol. 18, Feb. 2016
2015 Synthesis of multi-functional alkenes from substituted acrylates and aldehydes via phosphine-catalyzed Wittig reaction, Asian Journal Organic Chemistry, vol. 4, Sep. 2015
2015 An enantioselective synthesis ofsubstituted cyclohexane derivatives bearing an all-carbon quaternary stereocenter via organocatalytic asymmetric domino double Michael reaction, European Journal of Organic Chemistry, vol. 2015, Jul. 2015
2015 Preparation of Furo[3,2-c]coumarins from 3-Cinnamoyl-4-hydroxy-2H-chromen-2-ones and Acyl Chlorides: A Bu3P-Mediated C-Acylation/Cyclization Sequence, Angewandte Chemie International Edition, vol. 54, Jul. 2015
2015 Asymmetric organocatalytic synthesis of highly substituted cyclohexenols via domino double Michael reactions of 1-hydroxy-1,4-dien-3-ones and 2-alkylidene malononitirles, European Journal of Organic Chemistry, vol. 2015, Mar. 2015
2015 Organocatalytic Enantioselective Direct Vinylogous Michael Addition of alpha,belta-Unsaturated gamma-Butyrolactam to belta-Acyl Acrylates and 1,2-Dacylethylenes, The Journal of Organic Chemistry, vol. 80, Jan. 2015
2015 Base-Catalyzed Domino Double Michael Reactions of 1-Hydroxy-1,4-dien-3-ones and 2-Alkylidene Malononitirles: A Diastereoselective Route to Polysubstituted 4-Hydroxy-3-keto-cyclohex-3-enes, Synthesis-Stuttgart, vol. 47, Jan. 2015
2014 Chemoselective Intramolecular Wittig Reactions for the Synthesis of Oxazoles and Benzofurans, The Journal of Organic Chemistry, vol. 79, Dec. 2014
2014 Synthesis of Multi-Functional Alkenes via Wittig Reaction with a New-Type of Phosphorus Ylides, Tetrahedron, vol. 70, Aug. 2014
2014 Preparation of functionalized heteroaromatics using intramolecular Wittig reaction, Organic and Biomolecular Chemistry, vol. 12, Jun. 2014
2014 Direct β-Acylation of 2-Arylidene-1,3-indandiones with Acyl Chlorides Catalyzed by Organophosphanes, Chemical Communications, vol. 50, Apr. 2014
2013 Enantioselective Synthesis of Coumarin Derivatives Catalyzed by Primary Amine, Advanced Synthesis & Catalysis, vol. 355, Dec. 2013
2013 An Efficient Synthesis of Trisubstituted Oxazoles via Chemoselective O-acylations and Intramolecular Wittig Reactions, Chemical Communications, vol. 49, Nov. 2013
2013 Chemoselective Synthesis of Tetrasubstituted Furans via Intramolecular Wittig Reactions: Mechanism and Theoretical Analysis, Organic and Biomolecular Chemistry, vol. 11, Jul. 2013
2013 Facile synthesis of functional tricyclic fused furans via intramolecular Wittig reactions, European Journal of Organic Chemistry, vol. 2013, Jul. 2013
2013 Organocatalytic enantioselective direct vinylogous Michael addition of r-substituted butenolides to 3-aroyl acrylates and 1,2-diaroylethylenes, Chemistry - A European Journal, vol. 19, Jun. 2013
2013 A Versatile and Practical Method for Regioselective Synthesis of Polysubstituted Furanonaphthoquinones, Organic and Biomolecular Chemistry, vol. 11, Jan. 2013
2013 An efficient organocatalytic enantioselective synthesis of spironitrocyclopropanes, Organic and Biomolecular Chemistry, vol. 11, Jan. 2013
2012 Preparation of Functional Benzofurans and Indoles via Chemoselective Intramolecular Wittig Reactions, Chemical Communications, vol. 48, Aug. 2012
2012 Enantioselective organocatalytic Michael addition of ketones to alkylidene malonates, Chirality, vol. 24, Aug. 2012
2012 Enantioselective synthesis of substituted pyrans via amine-catalyzed Michael addition and subsequent enolization/cyclisation, Chemical Communications, vol. 48, Jun. 2012
2012 Preparation of Functional Phosphorus Zwitterions from Activated Alkanes, Aldehydes, and Tributylphosphine: Synthesis of Polysubstituted Furo[3,2-c]coumarins, Organic Letters, vol. 14, Apr. 2012
2012 Tandem Three-Component Reactions of Aldehyde, Alkyl Acrylate, and Dialkylmalonate Catalyzed by Ethyl Diphenylphosphine, Molecules, vol. 17, Mar. 2012
2012 Syntheses of furo[3,4-c]coumarins and related furyl coumarin derivatives via intramolecular Wittig reactions, Organic and Biomolecular Chemistry, vol. 10, Jan. 2012
2011 Preparation of Functional Benzofurans, Benzothiophenes, and Indoles Using Ester, Thioester, and Amide via Intramolecular Wittig Reactions, Organic Letters, vol. 13, Jun. 2011
2011 Organocatalytic tandem three-component reaction of imine, alkyl vinyl ketone, and imide via aza-Baylis-Hillman reaction, The Journal of Organic Chemistry, vol. 76, Apr. 2011
2011 A facile approach to highly functional trisubstituted furans via intramolecular Wittig reactions, Organic and Biomolecular Chemistry, vol. 9, Mar. 2011
2011 Organocatalytic Tandem Three-Component Reaction of Aldehyde, Alkyl Vinyl Ketone, and Amide: One-Pot Syntheses of Highly Functional Alkenes, Organic and Biomolecular Chemistry, vol. 9, Jan. 2011
2010 Tandem Three-Component Reaction of Aldehyde, Alkyl Acrylate and Amide Using Ethyl Diphenylphosphine as Organocatalyst, Tetrahedron Lett., vol. 51, Sep. 2010
2010 Preparation of Tetrasubstituted Furans via Intramolecular Wittig Reactions with Phosphorus Ylides as Intermediates, Organic Letters, vol. 12, Jul. 2010
2010 A New Type of Organocatalyst for Highly Stereoselective Michael Addition of Ketones to Nitroolefins on Water, Tetrahedron, vol. 66, Jan. 2010
年度 论文名称
2013 Synthesis of Functional Heteroarenes via Intramolecular Wittig Reactions, The First Asian Conference for “MONODUKURI” Strategy by Synthetic Organic Chemistry (ACMS), Jul. 17-19, 2013, Okinawa
2012 Preparation of Functional Phosphorus Zwitterions from Activated Alkanes, Aldehydes, and Tributylphosphine: Synthesis of Polysubstituted Furo[3,2-c]coumarins, The 7th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-7), Asian Core Program (ACP), Dec. 11-14, 2012, Singapore
2011 Facile Synthesis of Furans, Benzofurans, Benzothiophenes, Indoles, and [3,4-c] Furocoumarins via Intramolecular Wittig Reactions, 第六届亚洲尖端有机化学研讨会(ICCEOCA-6), Dec. 11-15, 2011, Hong Kong
2011 Investigation and Application of Wittig Reactions: Syntheses of Highly Functional Heteroarenes, 中国化学年会, Dec. 02-04, 2011, 新竹
2010 Preparation of Tetrasubstituted Furans via Intramolecular Wittig Reactions with Phosphorus Ylides as Intermediates, 第五届亚洲尖端有机化学研讨会(ICCEOCA-5), Nov. 07-11, 2010, 新竹
2010 Pyrrolidine-Type Organocatalysts Bearing Sulfone Moieties in Asymmetric Michael Addition Reactions, 第十一届Tetrahedron Symposuim, Jun. 22-25, 2010, 北京
年度 计画名称 参与人 职称/担任之工作 计画期间 补助/委讬或合作机构
2024 开发新颖的磷偶极体之合成方法及其应用在多官能基杂环分子之多样性导向合成 主持人 2023.08 ~ 2024.07 国科会
2023 开发新颖的磷偶极体之合成方法及其应用在多官能基杂环分子之多样性导向合成 主持人 2022.08 ~ 2023.07 科技部(原国科会)
2022 化学学门（有机组与无机组）研究发展推动计画(2/2) 国立台湾师范大学 协同/共同主持人 2022.01 ~ 2022.12 科技部(原国科会)
2022 开发新颖的磷偶极体之合成方法及其应用在多官能基杂环分子之多样性导向合成 主持人 2021.08 ~ 2022.07 科技部(原国科会)
2021 新型的磷偶极体和有机磷盐之制备及其应用在芳香杂环分子之合成 主持人 2020.08 ~ 2021.07 科技部(原国科会)
2020 新型的磷偶极体和有机磷盐之制备及其应用在芳香杂环分子之合成 主持人 2019.08 ~ 2020.07 科技部(原国科会)
2019 新型的磷偶极体和有机磷盐之制备及其应用在芳香杂环分子之合成 主持人 2018.08 ~ 2019.07 科技部(原国科会)
2018 发展新颖的有机磷诱导或催化反应:合成具官能基的杂环芳香族化合物 主持人 2017.08 ~ 2018.07 科技部(原国科会)
2017 有机催化Michael或连锁反应的研究:合成具光学活性香豆素衍生物 主持人 2016.08 ~ 2017.07 科技部(原国科会)
2017 发展新颖的有机磷诱导或催化反应:合成具官能基的杂环芳香族化合物 主持人 2016.08 ~ 2017.07 科技部(原国科会)
2016 发展新颖的有机磷诱导或催化反应:合成具官能基的杂环芳香族化合物 主持人 2015.08 ~ 2016.07 科技部(原国科会)
2016 有机催化 Michael 或 连锁反应的研究: 合成具光学活性香豆素衍生物 主持人 2015.08 ~ 2016.07 科技部(原国科会)
2015 有机催化 Michael 或 连锁反应的研究: 合成具光学活性香豆素衍生物 主持人 2014.08 ~ 2015.07 科技部(原国科会)
2015 磷试剂对亲电子性化合物进行Michael 加成或1,2-加成产生Wittig试剂 的研究及此类反应在有机合成上的应用 主持人 2014.08 ~ 2015.07 科技部(原国科会)
2015 多麸醯胺小脑萎缩症/阿兹海默氏症的药物开发－(子计画二)以粒线体新 生成及氧化压力为目标的多麸醯胺小脑萎缩症及阿兹海默氏症治疗策略(1/3) 化学系和医学系 协同/共同主持人 2014.05 ~ 2015.04 国科会
2014 磷试剂对亲电子性化合物进行Michael 加成或1,2-加成产生Wittig试剂 的研究及此类反应在有机合成上的应用 主持人 2013.08 ~ 2014.07
2013 磷试剂对亲电子性化合物进行Michael 加成或1,2-加成产生Wittig试剂 的研究及此类反应在有机合成上的应用 主持人 2012.08 ~ 2013.07 国科会
2012 重点一子题1及2：不对称有机催化Michael加成反应和三组分反应的研发 主持人 2011.08 ~ 2012.07 国科会
2012 新颖的醛（或亚胺）、高反应性的烯类及亲核性试剂所进行的三组分反应的研发：具有光学活性的β2-氨基酸的合成 主持人 2011.08 ~ 2012.07 国科会
2011 重点一子题1及2：不对称有机催化Michael加成反应和三组分反应的研发 主持人 2010.08 ~ 2011.07 国科会
2011 新颖的醛（或亚胺）、高反应性的烯类及亲核性试剂所进行的三组分反应的研发：具有光学活性的β2-氨基酸的合成 主持人 2010.08 ~ 2011.07 国科会
2010 多功能化的不对称有机催化剂的研发和其在有机合成上的应用 主持人 2009.08 ~ 2010.07 国科会
2009 多功能化的不对称有机催化剂的研发和其在有机合成上的应用 主持人 2008.08 ~ 2009.07 国科会
年度 名称 发表日期 全部作者
Phosphine-mediated Reactions 2015-08-08
Phosphine-catalyzed reactions 2014-09-01
Asymmetric organocatalysis 2014-08-01
国家 学校名称 系所 学位 期间
德国 德国慕尼黑大学 化学所 博士 2003.08 ~ 2006.11
台湾 国立台湾师范大学 化学系 硕士 1998.09 ~ 2000.06
台湾 国立台湾师范大学 化学系 理学士 1994.09 ~ 1998.06
台湾 台北市立建国高级中学 高中 1991.09 ~ 1994.06
台湾 台北县立海山国中 1988.09 ~ 1991.06
服务机关名称 单位 职务 期间
国立台湾师范大学 科学教育中心 主任 2024.08 ~ 迄今
科技部 (现为国科会) 化学学门/自然司 共同召集人 2022.01 ~ 2022.12
科技部 (现为国科会) 化学学门/自然司 审议委员 2020.01 ~ 2022.12
国立台湾师范大学 化学系 特聘教授 2020.01 ~ 2022.12
国立台湾师范大学 化学系 主任 2017.08 ~ 2019.07
科技部 化学推动中心/自然司 审议委员 2016.01 ~ 2020.12
国立台湾师范大学 贵重仪器中心 主任 2014.08 ~ 2017.07
国立台湾师范大学 化学系 特聘教授 2014.02 ~ 2016.07
国立台湾师范大学 化学系 教授 2014.02 ~ 迄今
国立台湾师范大学 化学系 副教授 2011.02 ~ 2014.01
国立台湾师范大学 化学系 助理教授 2008.02 ~ 2011.01
德国柏林科技大学 化学所 博士后研究 2007.01 ~ 2007.12
德国慕尼黑大学 化学所 博士后研究 2006.11 ~ 2006.12
国立台湾师范大学 化学系 助教 2002.03 ~ 2003.07
陆军(义务役军官) 少尉排长 2000.07 ~ 2002.03
类别 年度 奖项名称 颁奖单位
校外荣誉 2024 Asian Core Program Distinguished Lectureship Award Thailand
校外荣誉 2014 2014 Emerging Investigators 英国皇家化学学会
校内荣誉 2014 102年度研究绩优奖 国立台湾师范大学
校外荣誉 2013 Asian Core Program Distinguished Lectureship Award Thailand
校外荣誉 2013 杰出青年化学奖章 中国化学会
校外荣誉 2013 吴大猷先生纪念奖 行政院国家科学委员会
校外荣誉 2011 Asian Core Program Distinguished Lectureship Award Japan Society for Promotion of Sciences, JSPS