Minghuey Shieh
Name Minghuey Shieh
Email mshieh@ntnu.edu.tw
Office Tel No. (02)77496118
Personal Website https://ntnud405b.wixsite.com/mshieh
Title Distinguished Professor
Research Metal Cluster Chemistry, Organometallics, Material Chemistry, Computational Chemistry
Research Specialization Major goals of our research include synthetic, magnetic, electrochemical, and theoretical studies of heavier main group elements-containing transition metal carbonyl clusters and polymers.

Academic Researches

    1. M. Shieh,* Y.-H. Li, C.-H. Lin and T.-Y. Sun, “Low-Valent, Multiply Bonded, Trigonal-Planar Sb Complex: Rational Syntheses, Dual Acidic/Basic Properties, and Unexpected Semiconducting Characteristics,” InorgChem202059, 16073. [10.1021/acs.inorgchem.0c02820]
    2. M. Shieh,* Y.-H. Liu, T.-S. Lin, Y.-C. Lin, W.-K. Cheng and R. Y. Lin, “Manganese Telluride Carbonyl Complexes: Facile Syntheses and Exotic Properties—Reversible Transformations, Hydrogen Generation, Paramagnetic, and Semiconducting Properties,” Inorg. Chem. 2020, 59, 6923. [10.1021/acs.inorgchem.0c00412]
    3. M. Shieh,* Y.-H. Liu, Y.-H. Li and R. Y. Lin, “Metal Carbonyl Cluster-Based Coordination Polymers: Diverse Syntheses, Versatile Network Structures, and Special Properties,” CrystEngComm 201921, 7341. [10.1039/C9CE01539FBack Cover 
    4. M. Shieh,* Y.-H. Liu, C.-C. Wang, S.-H. Jian, C.-N. Lin, Y.-M. Chen and C.-Y. Huang, “A Comparative Study on NHC-Functionalized Ternary Se/Te–Fe–Cu Compounds: Synthesis, Catalysis, and the Effect of Chalcogens,” New J. Chem. 201943, 11832. [10.1039/c9nj02051a] 
    5. M. Shieh,* Y.-H. Liu, C.-C. Wang, S.-H. Jian, C.-N. Lin, Y.-M. Chen and C.-Y. Huang, “A Comparative Study on NHC-Functionalized Ternary Se/Te–Fe–Cu Compounds: Synthesis, Catalysis, and the Effect of Chalcogens,” New J. Chem. 201943, 12191[10.1039/C9NJ90106J] Back Cover
    6. M. Shieh,* Y.-H. Liu, C.-Y. Huang, S.-W. Chen, W.-K. Cheng and L.-T. Chien, “The First Naked Bismuth–Chalcogen Metal Carbonyl Clusters: Extraordinary Nucleophilicity of the Bi Atom and Semiconducting Characteristics,” Inorg. Chem. 201958, 6706. [10.1021/acs.inorgchem.9b00080Supplementary Cover
    7. M. Shieh,* Y.-H. Liu, Y.-H. Li, C.-N. Lin and C.-C. Wang, “Functionalized NHC-incorporated Te─Fe─Cu clusters: Facile synthesis, electrochemistry, and catalytic reaction,” J. Organomet. Chem. 2018867, 161. [10.1016/j.jorganchem.2017.10.039]
    8. M. Shieh,* C.-C. Yu, K.-J. Hsing and W.-J. Chang, “A Multiply Bonded Trigonal-Planar Bismuth(III) Complex: Prodigious Lewis Acidity, Solvatochromism, Etherification, and Semiconducting Characteristics,” Chem. Eur. J. 201723, 11677. [10.1002/chem.201702396]
    9. M. Shieh,* C.-C. Yu, C.-Y. Miu, C.-H. Kung, C.-Y. Huang, Y.-H. Liu, H.-L. Liu* and C.-C. Shen, “Semiconducting Coordination Polymers Based on the Predesigned Ternary Te─Fe─Cu Carbonyl Cluster and Conjugation-Interrupted Dipyridyl Linkers,” Chem. Eur. J. 201723, 11261.[10.1002/chem.201701257] Selected as a Hot Paper[10.1002/chem.201702641] Front Cover
    10. C.-N. Lin, C.-Y. Huang, C.-C. Yu, Y.-M. Chen, W.-M. Ke, G.-J. Wang, G.-A. Lee* and M. Shieh,* “Iron Carbonyl Cluster-Incorporated Cu(I) NHC Complexes in Homocoupling of Arylboronic Acids: An Effective [TeFe3(CO)9]2- Ligand,” Dalton Trans201544, 16675. [10.1039/c5dt03242c]
    11. M. Shieh,* C.-Y. Miu, K.-J. Hsing, L.-F. Jang and C.-N. Lin, “Copper-incorporated mono- and di-TeRu5 Metal Carbonyl Complexes: Syntheses, Structures, and An Unusual Skeletal Arrangement,” Dalton Trans201544, 6526. [10.1039/C5DT00546A]
    12. M. Shieh,* Y.-Y. Chu, L.-F. Jang and C.-H. Ho, “CO and CO2 Fixation by Se─Ru─CO Hydride Clusters,” Inorg. Chem201453, 4284. [10.1021/ic500821z]
    13. C.-N. Lin, W.-T. Jhu and M. Shieh,* “Vapochemically and Mechanochemically Reversible Polymerization/Depolymerization of S─Fe─Cu Carbonyl Clusters,“ Chem. Commun. 201450, 1134. [10.1039/c3cc48303g]
    14. M. Shieh,* C.-H. Yu, Y.-Y. Chu, Y.-W. Guo, C.-Y. Huang, K.-J. Hsing, P.-C. Chen and C.-F. Lee, “Trigonal Bipyramidal and Square Pyramidal Chromium─Manganese Chalcogenide Clusters [E2CrMn2(CO)n]2─ (E = S, Se, Te; n = 9, 10): Synthesis, Electrochemistry, UV/Vis Absorption, and Computational Studies,” Chem. Asian J. 20138, 963. [10.1002/asia.201201163]
    15. M. Shieh,* C.-Y. Miu, Y.-Y. Chu and C.-N. Lin, “Recent Progress in the Chemistry of Anionic Groups 6─8 Carbonyl Chalcogenide Clusters,” Coord. Chem. Rev. 2012256, 637. [10.1016/j.ccr.2011.11.010]
    16. M. Shieh,* C.-Y. Miu, K.-C. Huang, C.-F. Lee and B.-G. Chen, “Stepwise Construction of Manganese-Chromium Carbonyl Chalcogenide Complexes: Synthesis, Electrochemical Properties, and Computational Studies,” Inorg. Chem201150, 7735. [10.1021/ic200885h]
    17. M. Shieh,* Y.-Y. Chu, M.-H. Hsu, W.-M. Ke and C.-N. Lin, “Lead-Chromium Carbonyl Complexes Incorporated with Group 8 Metals: Synthesis, Reactivity, and Theoretical Calculations,” Inorg. Chem. 201150, 565. [10.1021/ic101560u]
    18. C.-H. Ho, Y.-Y. Chu, C.-N. Lin, H.-W. Chen, C.-Y. Huang and M. Shieh,* “Selenium─Manganese Carbonyl Clusters: Synthesis, Reversible Transformation, Electrochemical Properties, and Theoretical Calculations,” Organometallics 201029, 4396. [10.1021/om1006819]
    19. M.Shieh,* C.-N. Lin, C.-Y. Miu, M.-H. Hsu, Y.-W. Pan and L.-F. Ho, “Chromium-Manganese Selenide Carbonyl Complexes: Paramagnetic Clusters and Relevance to C=O Activation of Acetone,” Inorg. Chem. 201049, 8056. [10.1021/ic101118y]
    20. M. Shieh,* C.-H. Ho,W.-S. Sheu* and H.-W. Chen, “Selective Insertion of Oxygen and Selenium into an Electron-Precise Paramagnetic Selenium─Manganese Carbonyl Cluster [Se6Mn6(CO)18]4−,” J. Am. Chem. Soc2010132, 4032. [10.1021/ja9091566]
    21. M. Shieh,* Y.-Y. Chu, C.-Y. Miu, P.-F. Wu and T.-M. Zeng, “Bimetallic Ru-Cu Tellurido Complexes: Controlled Synthesis and Electrochemical Studies of Copper Halide-TeRu5 and Te2Ru4 Clusters,”Dalton Trans201039, 1492. (Selected as a Hot Article) [10.1039/b919176c]
    22. B.-G. Chen, C.-H. Ho, C.-J. Lee and M. Shieh,* “Copper Halide-Incorporated Tellurium─Iron Carbonyl Complexes: Transformation, Electrochemical Properties, and Theoretical Calculations,” Inorg. Chem. 200948, 10757. [10.1021/ic901647n]
    23. M. Shieh,* C.-H. Ho, W.-S. Sheu*, B.-G. Chen, Y.-Y. Chu, C.-Y. Miu, H.-L. Liu and C.-C. Shen, “Semiconducting Tellurium–Iron–Copper Carbonyl Polymers,” J. Am. Chem. Soc. 2008130, 14114. [10.1021/ja8065623]
    24. M. Shieh,* C.-Y. Miu, C.-J. Lee, W.-C. Chen, Y.-Y. Chu and H.-L. Chen, “Construction of Copper Halide-Triiron Selenide Carbonyl Complexes: Synthetic, Electrochemical, and Theoretical Studies,” Inorg. Chem200847, 11018. [10.1021/ic8012552]
    25. M. Shieh,* M.-H. Hsu, W.-S. Sheu, L.-F. Jang, S.-F. Lin, Y.-Y. Chu, C.-Y. Miu, Y.-W. Lai, H.-L. Liu and J.-L. Her, “A New Series of Copper Halide-Bridged Ruthenium Telluride Carbonyl Complexes: Discovery of a Unique Semiconducting Cluster Chain Polymer [{PPh4}2{Te2Ru4(CO)10Cu4Br2Cl2}·THF]¥,” Chem. Eur. J. 200713, 6605. [10.1002/chem.200700135]
    26. M. Shieh,* L.-F. Ho, P.-C. Chen, M.-H. Hsu, H.-L. Chen, Y.-W. Guo, Y.-W. Pan and Y.-C. Lin, “Reaction of [Et4N]2[Te{Cr(CO)5}n] (n = 2, 3) toward Electrophiles: Reactivity Comparison and Theoretical Calculations,” Organometallics 200726, 6184. [10.1021/om700789a]
    27. M.-H. Hsu, R.-T. Chen, W.-S. Sheu and M. Shieh,* “Carbon Dioxide Fixation by an Unprecedented Hydroxo Lead-Chromium Carbonyl Complex: Synthesis, Reactivity, and Theoretical Calculations,” Inorg. Chem. 200645, 6740. [10.1021/ic060554o]
    28. Y.-W. Lai, J.-J. Cherng, W.-S. Sheu, G.-A. Lee and M. Shieh,* “Novel Types of Organic S-Fe-CO Complexes: Reaction of [SFe3(CO)9]2- with Propargyl Bromide,” Organometallics 200625, 184. [10.1021/om050694q]
    29.  M. Shieh,* S.-F. Lin, Y.-W. Guo, M.-H. Hsu and Y.-W. Lai, “New Strategy to Mixed-Group 6 Metal Carbonyl Telluride Complexes: Completion of the Trigonal Bipyramidal Clusters [Te2CrM2(CO)10]2- (M = Cr, Mo, W),” Organometallics 200423, 5182. [10.1021/om049515f]
    30. M. Shieh,* H.-S. Chen and Y.-W. Lai, “Reaction of the Tellurium-Capped Triiron Cluster [TeFe3(CO)9]2- with the Bifunctional Propargyl Bromide: Formation of a Series of Novel Organic Te-Fe-CO Complexes, Organometallics 200423, 4018. [10.1021/om049712e]
    31. M. Shieh,* R.-L. Chung, C.-H. Yu, M.-H Hsu, C.-H. Ho, S.-M. Peng and Y.-H. Liu, “The Unusual Paramagnetic Mixed-Metal Carbonyl Chalcogenide Clusters: [E2Cr2Fe(CO)10]2- (E = Te, Se),” Inorg. Chem200342, 5477. [10.1021/ic034081m]
    32. M. Shieh,* L.-F. Ho, Y.-W. Guo, S.-F. Lin, Y.-C. Lin, S.-M. Peng and Y.-H. Liu, “Carbonylchromium Monotelluride Complexes [Et4N]2[Te{Cr(CO)5}n] (n = 2, 3): Two Important Intermediates,” Organometallics 200322, 5020. [10.1021/om034033+]
    33. M. Shieh,* Y. Liou, M.-H. Hsu, R.-T. Chen, S.-J. Yeh, S.-M. Peng and G.-H. Lee, “A Unique Bismuth-Iron Chain Polymer Containing the ...-Bi-Fe-... Link: Formation and Structure of [n-BuBiFe(CO)4]¥,”  Angew. Chem. Int. Ed. Engl. 200241, 2384; Angew. Chem. 2002114, 2490. [https://doi.org/10.1002/1521-3773(20020703)41:13<2384::AID-ANIE2384>3.0.CO;2-%23]
    34. M. Shieh,* J.-J. Cherng, Y.-W. Lai, S.-M. Peng and Y.-H. Liu, “Carbonylchromium Derivatives of Bismuth: New Syntheses and Relevance to C-O Activation,” Chem. Eur. J. 20028, 4522. [10.1002/1521-3765(20021004)8:19<4522::AID-CHEM4522>3.0.CO;2-7]
    35. J.-J. Cherng, Y.-W. Lai, Y.-H. Liu, S.-M. Peng, C.-H. Ueng and M. Shieh,* “Synthesis of Chromium Pentacarbonyl Dertives of Arsenic(V) and Antimony(V). Contrasting Chemical Reactivity with Organic Halogen Derivatives,” Inorg. Chem200140, 1206. [10.1021/ic0004277]
    36. M. Shieh,* H.-S. Chen, H.-Y. Yang, S.-F. Lin and C.-H. Ueng, “Tellurium-Bridged Manganese Carbonyl Clusters: Synthesis and Structural Transformations of [Te4Mn3(CO)10]-, [Te2Mn3(CO)9]2-, [Te2Mn3(CO)9]-, and [Te2Mn4(CO)12]2-,” Chem. Eur. J. 20017, 3152. [10.1002/1521-3765(20010716)7:14<3152::AID-CHEM3152>3.0.CO;2-B]
    37. M. Shieh,* L.-F. Ho, L.-F. Jang, C.-H. Ueng, S.-M. Peng and Y.-H. Liu, “First Selenium-Capped Carbonyltrichromium Complex [Se2Cr3(CO)10]2-: a Novel Cr3 Ring Cluster,” Chem. Commun2001, 1014. [10.1039/b101283p]
    38. M. Shieh,* H.-S. Chen, H.-H Chi and C.-H. Ueng, “Synthesis of an Se-Bridged Triiron Acyl Cluster Complex and the Fischer-Type Carbene Complex Derived from It: Isolation of Rotation Isomers,” Inorg. Chem200039, 5561. [10.1021/ic000301+]
    39. J.-J. Cherng, G.-H. Lee, S.-M. Peng, C.-H. Ueng and M. Shieh,* “Synthesis and Characterization of a New Series of Chromium-Group 15 Hydride Complexes [Et4N]2[H{Cr(CO)5}3]) (E = As, Sb), Organometallics 200019, 213. [10.1021/om990717z]
    40. M. Shieh,* H.-S. Chen, Y.-H Yang and C.-H. Ueng, “[Mn(CO)4TeMe25-Te)(μ4-Te)Mn4(CO)12]- : A Pentacoordinate Bridging Tellurido Ligand in a Square Pyramidal Geometry,” Angew. Chem. Int. Ed. Engl199938, 1252. [10.1002/(SICI)1521-3773(19990503)38:9<1252::AID-ANIE1252>3.0.CO;2-A